Silica in boiler feedwater precipitates and forms a hard, glossy coating on the internal surfaces. In the feedwater of high-pressure boilers, such as those used in electric generating plants, a certain amount of silica vaporizes under the influence of high pressure and temperature.
Start studying High and Low Pressure Boilers. Learn vocabulary, terms, and more with flashcards, games, and other study tools. Search. silica and iron that have dissolved into solution. High Pressure Boiler Operator. 101 terms. High Pressure Boilers 5th ed 1: CD exams.
In a phosphate precipitation treatment program, the magnesium portion of the hardness contamination is precipitated preferentially as magnesium silicate. If silica is not present, the magnesium will precipitate as magnesium hydroxide. If insufficient boiler water alkalinity is being maintained, magnesium can combine with phosphate.
If silica is present in the feedwater, it tends to precipitate directly as scale at hot spots on the boiler metal and or combines with calcium forming a hard calcium silicate scale. In the internal treatment for silica, the boiler water alkalinity has to be kept high enough to hold the silica in solution.
Vaporous carryover is silica's primary transport mechanism. Silica will precipitate in the high-pressure end of the turbine as steam pressure decreases during its path through the turbine blades.
pressure boilers. But carryover increases sharply with higher pressures. At 2000 psi, about 5% of the silica in the boiler water carries over into the steam. So operators at the Lower Mount Bethel plant aim keep the silica content in the high pressure boiler water below 200 ppb, preferably below 100 ppb. This
Other important area of concern as far as silica deposition is concerned is boiler tube. Silica scale is one of the hardest scale to remove. Because of its low thermal conductivity, a very thin silica deposit can reduce heat transfer considerably, reducing efficiency, leading to hot spots and ultimately ruptures.
Silica (SiO2) can volatilize with the steam in sufficient concentrations to deposit in steam turbines leading to scale formation on boiler surfaces. In this work, a simple correlation is presented to predict silica (SiO2) solubility in steam of boilers as a function of pressure and water silica content.
For high silica waters in high pressure steam boilers, it is important to maintain a 3:1 total alkalinity to silica ratio to prevent silica from plating on your boiler tubes. If you are using an all polymer scale prevention chemical it is also important to keep the boiler water pH above 10.5 to ensure the polymer properly works at capturing
Jul 24, 2017 · This includes installing trays of desiccant, such as silica gel, in the boiler drums to maintain a constant low humidity atmosphere. The boiler is then closed to minimize oxygen ingress. If the boiler is to be stored open, the boiler and superheater are thoroughly dried and a positive dry air flow is maintained from bottom to top during the storage period.
Fire Tube Boilers. Also referred to as smoke tube boilers, shell boilers, package boilers Multiple gas paths - 2, 3 and 4 pass Internal furnace or fire box as the 1st pass Dry back or wet back design Single fuel or dual fuel design Little or no steam separation equipment.
When boilers are designed to operate at very high pressures, they are not designed to operate under even the slightest vacuum. A potential vacuum is created when a boiler is shut down. As the unit cools, the steam condenses and water level drops, which allows the pressure to drop.
Silica Scaling in Boilers Silica , in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. In rain hail and snow, silica content range from 1 to 2.8 ppm.
Silica is one of the major scale forming elements in boiler water chemical regime (WCR) of thermal power industry. Carryover of silica is also another serious problem, particularly in high pressure and critical pressure boilers, Hence, generally the medium-pressure, high-pressure and critical-pressure boilers are equipped with super heaters and turbine. Silica in steam can result from mechanical carryover
Impurity in Steam Affect: - High silica in steam - Phosphate carry over - High level of water in drum Affect: - Solids carry over in steam will lead to deposits on turbine blades, increase of first stage pressure and increase of axial shift of turbine rotor Corrective Action: - Monitor boiler water chemistry and operate CBD as per chemist’s recommendation - Reduce drum pressure to prevent carry over of silica in steam -
High-pressure boilers will heat steam above 15 psi and water at pressures that exceed 160 psig. Temperatures in high-pressure boilers will exceed 250 degrees F. Because of the elevated pressure at which these boilers operate, they need to be monitored to ensure safety at all times.
– Rotating machinery that efficiently converts heat energy to mechanical energy to turn a generator that makes electrical energy. – Pressure and temperature are reduced in the process, hence high pressure and low pressure sections. – Steam purity and proper boiler water chemical and
scale. The most common components of boiler deposits are calcium phosphate, calcium carbonate (in low-pressure boilers), magnesium hydroxide, magnesium silicate, various forms of iron oxide, silica adsorbed on the previously mentioned precipitates, and alumina (see Table 39.1). If
Dec 22, 2016 · Boiler Water. For example, in a 1000 psi boiler the recommended maximum drum water silica concentration is 2.3 ppm. In a 2,400 psi steam generator the recommended maximum is 0.22 ppm! But again to re-emphasize, the allowable limits for silica and many of the other impurities are based on protection of steam purity.
Jan 29, 2017 · Lecture Series on Steam and Gas Power Systems by Prof. Ravi Kumar, Department of Mechanical & Industrial Engineering, Indian Institute of Technology Roorkee, Uttarakhand, India.
any water carryover is occurring is to measure the conductivity of the steam or of the. steam condensate. If you detect less than 25 micromhos conductivity in the condensate, then carryover is
Silica is one of the major scale forming elements in boiler water chemical regime (WCR) of thermal power industry. Carryover of silica is also another serious problem, particularly in high pressure and critical pressure boilers, Hence, generally the medium-pressure, high-pressure and critical-pressure boilers are equipped with super heaters and
Problems That Lead To High Boiler Pressure. Below are the top causes of high boiler pressure. If you’re constantly having problems with your boiler and would prefer a new one with a long warranty, check out BOXT. They’re a boiler installation company part owned by Bosch, so install Worcester boiler boilers at competitive prices.
May 22, 2017 · Answer Wiki. The deposition is mainly depends on the silica percentage in boiler feed water . water consists the silica which goes to steam drum in which steam and water separation takes place . The unwanted materials in water are settle at the bottom of the steam drum. Deposit in steam drum can remove by giving the blow down.
Impurity in Steam Affect: - High silica in steam - Phosphate carry over - High level of water in drum Affect: - Solids carry over in steam will lead to deposits on turbine blades, increase of first stage pressure and increase of axial shift of turbine rotor Corrective Action: - Monitor boiler water chemistry and operate CBD as per chemist’s
When a boiler is stored dry, desiccant should be placed in the boiler drums along with the nitrogen blanket to absorb any free moisture. Always ensure that the steam drum vent valve is opened whenever the boiler pressure is less than 5 psig. In summary, a boiler is much like the human body.
and vapour phases in a boiler. As the temperature and pressure are increased, more silica becomes present in the steam. In high pressure boilers, therefore, silica is appreciably concentrated in the steam and this is when 'carry-over' may occur, being deposited later, on the superheaters or turbine blades. Silica entering a high pressure boiler can concentrate very quickly. An impurity
Colloidal silica will show up very little even in the chemical test, as it is a polymer and quite unreactive. Once it goes into your boiler, it is hydrolysed under high temperature and high pH of the boiler water and appears as if by magic, as suddenly it is monomeric and able to react with the test method.
Boiler Blowdown. 1) The International Association of Plumbing and Mechanical Officials ( IAPMO) develops the Uniform Plumbing Code (UPC) which is widely adopted in western United States. Due to high pressure and temperature in the boilers - large amounts
Sep 26, 2016 · Silica: if not removed to low levels, especially in high-pressure boilers, silica can cause extremely hard scaling Calcium: can cause scaling in several forms depending on the chemistry of the boiler feed water (e.g. calcium silicate, calcium phosphate, etc.)
Sludge is the accumulation of solids that precipitate in the bulk boiler water or enter the boiler as suspended solids. Sludge deposits can be hard, dense, and tenacious. When exposed to high heat
Sep 24, 2003 · It's been many years since my chemistry in power plants, but as I recall, silica is a cation and your anion bed won't remove it your initial <2 ppb concentration will concentrate in the boiler drum which your blowdown is suppose to remove -- I would suspect that by recycling your boiler blowdown through an anion bed instead of a mixed bed (or two-bed), you are re-introducing the silica into your
•Pressure range – 60-84 bar • Critical needs – High quality makeup water • External pre-treatment through distillation and mechanical deaeration – High purity steam to the turbine – No excess hydrate alkalinity – Precise control of total system water treatment High Pressure Boilers • Steam cycle
Silica Silicates are forming silicate deposits, while the present a kind of volatility. So an amount of silica escapes to the steam, and when steam condenses, it is deposited as pure solid silica.. For High pressure boilers, we suggest you to use the relationship: NCmax=Max SiO 2 (boiler)/SiO2(MU)
Apr 27, 2015 · Water Treatment Requirements for Low and Medium Pressure Boilers by William (Bill) Harfst April 27, 2015 Low and medium pressure boilers must be protected from scale deposition and corrosion to promote optimum energy efficiency and prolong the useful life of the plant equipment.
Steam and water analysis system (SWAS) is a system dedicated to the analysis of steam or water.In power stations, it is usually used to analyze boiler steam and water to ensure the water used to generate electricity is clean from impurities which can cause corrosion to any metallic surface, such as in boiler
Nalco addresses water conditions related to hardness, oxygen, silica, iron and more. In low pressure boilers internal treatment may be the only treatment necessary because much of the condensate is returned and the raw water is of good quality. Moderate and high pressure boilers require both external pretreatment and internal treatment. Deposit
•Silica –normal saturated steam should be < 20 ppb in most boilers. High pH in the boiler water will reduce silica carryover from the boiler water. Monitor the steam because: •Precipitation of silica forms silicate deposits on the cold end of the turbine that are not water soluble and are very difficult to remove.
Apr 17, 2018 · Such deposits may contain calcium, magnesium, phosphate, iron, and silica. A tenacious form of boiler scale results when calcium precipitates in the form of calcium carbonate. Boiler sludge is a deposit that forms when suspended materials present in the boiler water settle on, or adhere to, hot boiler tubes or other surfaces.