oxygen solubility in hot water boiler

How exactly does dissovled oxygen affect water quality

Water used in very low pressure boilers have no more than 2.0 ppm of DO, but most boiler plant operators try to keep oxygen levels to 0.007 ppm or less. Dissolved oxygen (DO) refers to the amount of oxygen dissolved in water and is particularly important in limnology (aquatic ecology). Oxygen comprises approximately 21% of the total gas in the atmosphere; however, it is much less available in water.

Recommended ABMA & ASME Boiler Water Limits Boiler

In boiler systems, that environment includes hot water with a low pH or slightly acid condition and some degree of oxygen entrainment. Those conditions are ideal for corrosive action. Removal of carbon dioxide and oxygen from boiler feedwater is essential to preventing boiler-system corrosion.

Oxygen and Pressure Tables - Water Quality Sampling and

Oxygen and Pressure Tables Author: YSI Subject: Oxygen solubility table, pressure calibration table Keywords: oxygen table Created Date:

Oxygen Control For High- and Low-Pressure Boiler Water

for Commercial and Institutional boiler water systems and the mechanical and chemical best practices for maintaining those systems. H1 Dissolved Gases and Dissolved Oxygen Corrosion Control The dissolved gases present in water, specifically oxygen, cause boiler water systems prone to problems with dissolved oxygen corrosion if gone untreated.

Boiler Oxygen Scavengers - Prevent Boiler Rust

Boiler Oxygen Scavengers are used to remove dissolved oxygen from the boiler feed water and boilers. Dissolved oxygen in the boiler is very corrosive at higher temperatures and pressures. This may lead to localized pitting and premature boiler tube failure or excessive feedwater leaks.


In the conventional type, a. hot water boiler is used to provide heat to the circulating system. The second type involves the use of a convertor (i.e. heat exchanger) to indirectly heat the closed hot water system, the heat to the convertor being supplied in most cases by steam from a steam boiler.

Properly Treat Boiler Water for Efficient, Long -Term

Boiler feedwater also contains dissolved gases, such as carbon dioxide and oxygen, that react in a boiler and lead to corrosion of the boiler internals and the piping system. If these gases are not extracted from the water supply before entering the boiler, the corrosion will eventually eat through boiler tubes and cause leaks and equipment failure.

Boiler Water Treatment & Chemical Treatment | Chardon Labs

The solubility of oxygen in water is inversely proportional to temperature. That is, the hotter the water, the less oxygen it will hold. The goal of any feedwater treatment program is to reduce the amount of oxygen in the feedwater so that as little as possible enters the boiler.


water has been in equilibrium with the atmosphere and the solubility of oxygen and nitrogen has been proportional to the concentration of oxygen and nitrogen in the atmosphere. In the raw water, this corresponds to 8-10 ppm of oxygen. In the deaerator, the water equilibriates with steam. As

Condensate Water Treatment: Because Steam Boiler Pipes Are

Neutralizing amines are used in boiler water treatment to control condensate return line corrosion. The amines do not have any adverse effects on copper or copper alloys under normal treatment conditions where pH is maintained between 7.5 to 9.0 and where only a

DOTABLES - Water Resources

The salinity correction factor is the ratio of the solubility of oxygen in water at a particular salinity to its solubility in fresh water at an identically specified water temperature and barometric pressure.

Deaerator In Boiler Feedwater System-ZBG Boiler

Deaerator In Boiler Feedwater System. It accomplishes this by reducing the concentration of dissolved oxygen and carbon dioxide to a level where corrosion is minimized. A dissolved oxygen level of 5 parts per billion (ppb) or lower is needed to prevent corrosion

Sulfites for Oxygen Control - Scranton Associates

of oxygen and hot feedwater about 3 mg/L. A variation from 40° F to 80° F in our water source results in a drop in oxygen content from 13 ppm to 8 ppm. Concentrations of oxygen are usually expressed as cubic centimeters per liter (cc/L) or milliliters per liter (ml/L) [numerically the same]. Oxygen may also be reported by weight: 1 cc/L or ml/L

13.4: Effects of Temperature and Pressure on Solubility

Because of the reduced solubility of \(O_2\) at higher temperatures (Figure \(\PageIndex{2}\)), the warmer water contains less dissolved oxygen than the water did when it entered the plant. Fish and other aquatic organisms that need dissolved oxygen to live can literally suffocate if the oxygen concentration of their habitat is too low.

How exactly does dissovled oxygen affect water quality

Water used in very low pressure boilers have no more than 2.0 ppm of DO, but most boiler plant operators try to keep oxygen levels to 0.007 ppm or less. Dissolved oxygen (DO) refers to the amount of oxygen dissolved in water and is particularly important in limnology (aquatic ecology).

How water behaves in hydronic systems - HPAC Magazine

How water behaves in hydronic systems Tags. hydronic water chemistry a molecule of bonded sodium and chloride, is placed in water. The powerful forces of water’s oxygen and hydrogen atoms dissolve the salt by breaking the sodium chloride bond. One cast iron boiler manufacturer specifies a 10.5 pH maximum for their boiler. Fresh water

Dissolved oxygen corrosion

Dissolved oxygen (DO) refers to the volume of oxygen that is contained in water. Oxygen enters the water by photosynthesis of aquatic biota and by the transfer of oxygen across the air-water interface. The amount of oxygen that can be held by the water depends on the water

What is an Oxygen Attack? - Definition from Corrosionpedia

Aggressiveness generally increases with an increase in oxygen. Oxygen control is generally both a mechanical and chemical process. The majority of oxygen in the boiler feedwater is typically reduced to less than 20 parts per billion (ppb) by heating the water to reduce its solubility.

Water Handbook - Preboiler & Industrial Boiler Corrosion

At 60°F and atmospheric pressure, the solubility of oxygen in water is approximately 8 ppm. Efficient mechanical deaeration reduces dissolved oxygen to 7 ppb or less. For complete protection from oxygen corrosion, a chemical scavenger is required following mechanical deaeration.

The importance of pH in steam-boiler water - Heating Help

Jun 24, 2014 · That oxygen comes out of solution as the water boils, and it can eat holes in the boiler, right at the boiler’s waterline. If you decide to feed with hot water instead of cold water, the minerals in the water will come out of solution on the automatic water-feeder’s seat, and that can cause a flood, especially if it’s a one-pipe-steam system.

9707 Key West Avenue - Home | The Association of Water

of 70 °F will dissolve approximately 8 mg/L of oxygen. increased to 140 °F, the water will only be capable of dissolving 5 mg/L of oxygen. other 3 mg/L of dissolved oxygen is driven out of the water into the above air. water is heated still further to 200 °F, it will dissolve less than 2 mg/L of oxygen.

Boiler Water Treatment Part 2 – Internal Treatment

Boiler Water Treatment Part 2 – Internal Treatment Objectives of Internal Water Treatment 1 – To control the level of total dissolved solids (TDS) within the boiler oxygen by de-aeration in the boiler feed tank. In most cases an oxygen scavenger will also be used.

Volatile Oxygen Scavenger for Boilers, Steam Raising Plant

volatile oxygen scavenger for boilers, steam raising plant and hot water systems. Accepta 2561 is a low toxicity boiler treatment that removes dissolved oxygen from the feed water, boiler water and condensate lines and can be used in medium pressure hot water

How water behaves in hydronic systems - HPAC Magazine

Even at extremely low oxygen levels, metals can corrode if pH stays below or above a “happy range” for that metal. Non-alloyed aluminum has a happy range of 6.5 to 8.5 pH. For stainless steel the range is generally higher. One stainless boiler manufacturer specifies an acceptable range of 6.5 to 9.5 pH.

Deaerator | CleanBoiler.org

Simply stated, the steam heats the water, and at the elevated temperature the solubility of oxygen is extremely low and most of the dissolved gases are removed from the system by venting. The spray will reduce the dissolved oxygen content to 20-50 ppb, while the scrubber or trays further reduce the oxygen content to approximately 7 ppb or less.

Sodium Sulphite Boiler Water Oxygen Scavenger – 2326

Accepta 2326 - Sodium Sulphite Boiler Water Oxygen Scavenger. This high performance product rapidly reacts with oxygen ensuring efficient protection of feedlines and boilers from corrosion and enhancing protection against caustic embrittlement. Technically advanced, Accepta 2326 has been formulated for those applications such as the food industry where heavy metal catalysts cannot be used.

Air Solubility in Water - Engineering ToolBox

The solubility of oxygen in water is higher than the solubility of nitrogen. Air dissolved in water contains approximately 35.6% oxygen compared to 21% in air. Solubility of Air in Water. Solubility of air in water - expressed as ratio of absorbed air volume to water volume:

Chapter 10 Boiler Feedwater Deaeration - GE Water is now SUEZ

In order to deaerate the boiler feedwater, water is sprayed into a steam atmosphere. This heats the water to within a few degrees of the temperature of the saturated steam. Because the solubility of oxygen in water is very low under these conditions, 97 to 98%


In order to deaerate the boiler feedwater, water is sprayed into a steam atmosphere. This heats the water to within a few degrees of the temperature of the saturated steam. Because the solubility of oxygen in

28 — DO - Water Resources

Dissolved Oxygen U.S. Geological Survey TWRI Book 9 4/98 28 — DO Table 6.2–6. Solubility of oxygen in water at various temperatures and pressures [From R.F. Weiss (1970). Temp °C, temperature in degrees Celsius; atmospheric pressures from 695 to 600 millimeters

Hot-Water- and Steam-Boiler Water Treatment | HPAC Engineering

Steam boilers tend to be steel water-tube- or fire-tube-type boilers in the 10-to-1,000-hp range. Fire-tube boilers are more robust and more tolerant of poor water quality, but require more physical space, than water-tube boilers. Regardless of boiler type, water quality is a critical aspect of implementing and operating an efficient steam plant.

Boiler Chemistry Control and Treatment of Feed Water

May 05, 2015 · Ammonia is commonly used cheaper material to maintain pH in boiler water. N 2 H 4 is used to scavenge Dissolved Oxygen and protect Copper alloys from Ammonia. It may be good for Cu alloy but form thick harder magnetite layer.

Hot vs. cold water feed for steam boiler? — Heating Help

When I bought my house in 2002 the boiler was fed with hot water. I am now doing some work and have the choice to leave it that way or switch it to cold. I think that one reason to use hot water is that it should already have some of the oxygen removed due to the fact that the solubility of gas in water decreases as temperature rises.

Water Handbook - Preboiler & Industrial Boiler Corrosion

Iron can enter the boiler as soluble ferrous ions and insoluble ferrous and ferric hydroxides or oxides. Oxygen-free, alkaline boiler water converts iron to magnetite, Fe 3 O 4. Migratory magnetite deposits on the protective layer and is normally gray to black in color. Copper Oxide Formation

Dissolved Oxygen Scavenger Dosing Calculations For Water

Jan 26, 2013 · In oil-production environments where produced water is re-used to generate steam, the water often contains significant salt quantities that alter the solubility of oxygen. Some produced waters also contain organic species that create a chemical oxygen demand (COD), which may actually reduce the dissolved O2 to very low levels, making active scavenger dosing easier or potentially unnecessary.

Deaerator Design and Operation - chemaqua.com

A deaerator preheats boiler feedwater and removes dissolved gases, especially oxygen and carbon dioxide. These gases are undesirable because they cause corrosion and increase treatment chemical requirements. Operation. Deaerators operate based on the reduced solubility of dissolved gases as temperature increases.

Reducing Corrosion and potential Boiler Failure with

water, a tightly adherent magnetite layer is formed, which is indicative of a well-passivated iron surface. In the absence of contaminants, this oxide layer greatly retards any further oxidation reactions. 2.1.1. Pre-boiler Oxygen Corrosion In the presence of oxygen, the corrosion process described above is modified.

13.4: Effects of Temperature and Pressure on Solubility

Due to the low Henry’s law constant for \(O_2\) in water, the levels of dissolved oxygen in water are too low to support the energy needs of multicellular organisms, including humans. To increase the \(O_2\) concentration in internal fluids, organisms synthesize highly

Corrosion in boilers - Lenntech

Corrosion in boilers. Corrosion may occur in the feed-water system as a result of low pH water and the presence of dissolved oxygen and carbon dioxide. Starting form these figures, and allowing the amount that can be blown down, the permitted concentration in the make-up water is thus defined.


iron and steel components are caused by excessive oxygen in the boiler/feedwater. The accumulations of corrision products covered by unique nodules are called “tubercles.” 2.2.5 Iron, eaten away by “acid rain” and oxygen corrosion, is transported to the boiler, where it becomes an insulating deposit. It restricts heat transfer, which can